no. If you want to work with Thai businesses you would have to give up the DTV and change to a Non-B visa with a work permit. Either you work i. Thailand for a Thai entity or you work remotely for a non-thai entity located outside of Thailand. There is no visa that allows you to do both
Nothing happens as you won't be issued a 2nd visa in that way. You need to attend immigration and apply to change your visa from one type to the other. I assume the BOI can advise you on how to do this since they are the ones that issue LTR visas
Their website quotes 7 working days BUT it also says it only processes applications from those with a right of residence in Hong Kong. Assuming you do and they process your application you need to remain there until the process completes
I don't think you can get the ID card unless you are married to a Thai or have purchased a condo as you first need to get a yellow house book but the requirements for obtaining the house book vary by area so best to ask your local office. On a tourist visa like the DTV I can't see another way for you. A Thai driving licence is accepted as ID virtually everywhere
If you are doing this every year then your chances of being denied entry increase. It's not a good plan for living inside Thailand 6 months of every year